HOME教員情報物質化学工学科川淵 浩之


川淵 浩之

川淵 浩之教授

かわふち ひろゆき





  1. TEMPO分子を活用する官能基変換に関する研究
  2. ハロゲン置換芳香族化合物の電解脱ハロゲン化反応に関する研究
  3. 酵素モデル金属錯体を用いる生体反応を模範とする電解反応プロセスの開発


  1. 有機合成化学
  2. 有機電解合成


  • H. Kawafuchi, L. Ma, M. I. Hossain, and T. Inokuchi, O-AcyITEMPOs, a Modified and Fundamental, but Unexplored Carboxylic Derivative: Recent Progress in Synthetic Applications: Current Organic Chemistry, Vol. 23, pp. 2102-2121 (2019).
  • 川淵 浩之, 馬 利建, 井口 勉, アシル置換基修飾型カルボン酸誘導体としてO-アシルTEMPOおよび関連化合物の反応性と応用展開:有機合成化学協会誌,Vol.73, No.10, pp.995-1006(2015).
  • M.-Y. Wu, E. Shaban, M. Switalska, N. Wang, M. Shimoda, Y. Mizutani, Z.-W. Mei, H. Kawafuchi, J. Nokami, J. Wietrzyk, X.-Q.Yu, and T. Inokuchi, Synthetic Access to Poly-Substituted 11H-Pyrido[3,2-a]Carbazoles, a DNA-Intercalating Ellipticine Related Structure, and Their Antiproliferative Activity: Heterocycles, Vol.89, No.6, pp.1427-1440 (2014).
  • E. Shaban, M. I. Hossain, M.-Y. Wu, Y. Takemasa, S. Nagae, W. Peng, H. Kawafuchi, and T. Inokuchi, Microwave-Irradiated Synthesis of 1,2-Dihydropyridines from N-Functionalized Enaminones and Enals through Domino Condensation and 6π-Azaelectrocyclization: Heterocycles, Vol.89, No.1, pp.171-182 (2014).
  • M. I. Hossain, E. Shaban, T. Ikemi, W. Peng, H. Kawafuchi, and T. Inokuchi, Annulation of 2H-Pyran onto 1-Oxa- or 1-Aza-cyclohexane-2,4-diones and Their Analogues via Sequential Condensation with α-Substituted Enals and 6π-Electrocyclization: Bulletin of the Chemical Society of Japan, Vol.86, pp.870-879 (2013).
  • W. Peng, T. Hirabaru, H. Kawafuchi, and T. Inokuchi, Substituent-Controlled Electrocyclization of 2,4-Dienones: Synthesis of 2,3,6-Trisubstituted 2H-Pyran-5-carboxylates and Their Transformations: European Journal of Organic Chemistry, Vol. 2011, pp. 5469-5474 (2011).
  • L.-J. Ma, Z.-W. Mei, K. Toyohara, H. Kawafuchi, J. Nokami, and T. Inokuchi, Diastereoselective Michael Addition of Magnesium Amide to O-(2-Alkenoyl)TEMPOs and Comparison of Reactivity with Acyl Substituent-Modified Carboxylic Analogues: Bulletin of the Chemical Society of Japan, Vol. 83, No. 12, pp.1545-1547 (2010).
  • Z.-W. Mei, L.-J. Ma, H. Kawafuchi, T. Okihara, and T. Inokuchi, TEMPO-Mediated Oxidation of Primary Alcohols to Carboxylic Acids by Exploitation of Ethers in an Aqueous–Organic Biphase System: Bulletin of the Chemical Society of Japan, Vol. 82, No. 8, pp.1000-1002 (2009).
  • Z.-W. Mei, T. Omote, M. Mansour, H. Kawafuchi, Y. Takaguchi, A. Jutand, S. Tsuboi, and T. Inokuchi, A High Performance Oxidation Method for Secondary Alcohols by Inductive Activation of TEMPO in Combination with Pyridine-Bromine Complexes: Tetrahedron, Vol. 64, pp.10761-10766 (2008).
  • 川淵 浩之, 臭素化エポキシ樹脂の再資源化を目的とした電解脱臭素化反応の開発: 化学工業, Vol. 59, No. 7, pp.86-91 (2008).


  • 有機化学, 実教出版(平成27年).
  • これでわかる基礎有機化学演習, 三共出版株式会社 (平成24年).
  • これでわかる基礎有機化学, 三共出版株式会社 (平成18年).